Russian Coatings Journal

CONTENTS

4, 46 NEWS

PRODUCTS AND RESEARCH
10 Stability and coagulation of mixed water dispersions of mineral powders and latexes — Prof. Koshevar V. D., PhD Kazhuro I.P.
Abstract:
Systematic study of aggregate stability and coagulation of water binary mixtures of synthetic latexes and mineral powders of different chemical nature and particles sizes depending on the charge and electro kinetic potential of particles, concentration of disperse phases and pH of dispersion medium was performed using photo-sedimentation, differential-thermal, turbidimetry, ζ-photometry, IR-spectroscopy and scanning electron microscopy methods. High aggregate stability of mixed dispersions of acrylic, styrene-butadiene latexes with kaolin and titan dioxide in basic media was established, it is reasoned by the localization of latex particles of colloidal size near negatively charged mineral particles. In acid media (pH=3.5) substantial drop of aggregate stability of these binary systems accompanied by the formation of flaky non-dispersible precipitate as a result of homo- and hetero-coagulation processes taking place. The stability of binary mixtures of all investigated latexes and microcalcite is much less dependent of chemical nature of latexes and changes of pH of the medium. Possible reasons of such behavior of the compositions being
studied are discussed.
Keywords: kaolin, titanium dioxide, microcalcite, latexes, mixed dispersions, aggregate stability, electro kinetic
potential, heterocoagulation.

34 Photo-curing paints for optical fiber production — Prof. Babkin O. E., Babkina L. A., Il’ina V. V., Aykasheva O. S., Izotova K. V.
Abstract
article presents the results of research in the field of creating photo-curable paints formulations for color marking of optical cable fibers. Basic compositions of epoxy acrylate lacquer with pigment pastes, which differ in photoinitiation systems, are considered. Based on the analysis of the completeness of the polymerization of the obtained coatings, conclusions were drawn about the efficiency of the considered systems.
Keywords: photo-curable paints, optical fiber, optical cable production.

ECONOMICS AND STATISTICS
19 Water-based materials in the industrial sector: prospects and challenges

RAW MATERIALS. SEMI PRODUCTS AND COATINGS
23 Organic Pigments by SunChemical for Water-based coatings — Nikitina S., Demenok A.

ECOLOGY AND RESOURCE EFFICIENCY
31 Green strategy of MÜNZING CHEMIE — Chernogorova M.

EVENTS
26 In spite of the pandemic. INTERLAKOKRASKA celebrated its anniversary

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CONTENTS

4, 48 NEWS

PRODUCTS AND RESEARCH
13 Additives for coatings: present and future

20 Method for increasing the hardness of 1K aliphatic PU coating — Antipova E. A., Korotkova N. P., Styunina A. O.
Abstract:
In this paper, the influence of the concentration of rigid segments in a PU elastomer on its technological and physical-mechanical properties, as well as on chemical resistance, is investigated. The study was carried out using PU-elastomeric binders synthesized on the basis of aliphatic polyester with MM 2000 and functionality 2, aliphatic polyisocyanate and chain extension. On the basis of these components, a number of pre-polymers with a mass fraction of NCO groups of 8.5% and different concentrations of rigid segments were synthesized. The synthesis of the pre-polymers was carried out according to a well-known technology at a temperature of 70–80 °C.
The physical and mechanical properties of the cured material were studied on films that were prepared by pouring a pre-polymer solution in a system of solvents methyl ethyl ketone : xylene = 60 : 40 into glass molds treated with an anti-adhesive. The films were formed under the following conditions: 1 day at the temperature and humidity of the room; 12 hours — in a thermal cabinet at 80 °C. The complete curing of the films was controlled by the gel-fraction method (extraction with acetone in the Soxlet apparatus). The gel fraction in the samples was no more than 4%, which indicates a degree of curing of >95%. The obtained films were tested on the machine «Instron 3369» according to GOST 270-75.
The protective properties of PU film samples were evaluated at room temperature by the value of the equilibrium degree of swelling in the following media: distilled water, transformer oil.
The adhesion of the cured coatings to glass and stainless steel was determined by the cross cut method in accordance with GOST 15140-78.
Optimization of the concentration of rigid segments allowed the development of a new 1K aliphatic PU binder for obtaining UV-resistant coatings with high hardness, strength, adhesion and chemical resistance.

Keywords: polyurethanes, anti-corrosion coatings, UV-resistant coatings.

36 Fillers for modification of polyester powder paints

INTERVIEW
24 Under reliable protection

EXPERT VIEW
26 Issues of standardization in the paint and varnish industry — Averyanov G. V.

POINT OF VIEW
29 Unexpected properties of traditional pigments — PhD Kaverinsky V. S., Kaverinsky D. V.

ECOLOGY AND RESOURCE EFFICIENCY
39 Paint and varnish companies are preparing for tougher regulation

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CONTENTS

4, 45 NEWS

ECOLOGY AND RESOURESE EFFICIENTLY
9 Coatings for wooden surfaces: main trends — PhD Kaverinsky V. S., Kaverinsky D. V.

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
14 Deep black with NUOSPERSE ® FX 7500W dispersant
36 Synergistic effect of fillers in waterborne UV-curable coatings for interior use

PRODUCTS AND RESEARCH
16 Coatings with reduced adhesion to ice — Doctor of Technical Sciences Drinberg A. S., Tarasova I. N., Nedvedsky G. R., Candidate of Chemical Sciences Mametnabiev T. E., Litosov G. E., Alikin M. B., Okhrimenko A. G.
Abstract:
Of the many ways to prevent icing: thermal, mechanical, physical and chemical the most interesting is the use of anti-icing coatings, which are subject to a number of specific requirements, the main of them-reduced adhesion to ice. There are many approaches to creating coatings with reduced adhesion to ice. This includes the introduction of polysiloxanes, the use of fluorinated polymers or organosilicon. Also, one of the promising directions of creating such coatings is the use of superhydrophobic coatings. However, for comparative tests of various coatings, it was necessary to develop a special method for determining the adhesive strength to ice and it is desirable to display it in physical quantities by direct tests, rather than indirect (as the method of cross cut by GOST 31149-2014). The SPbGTI (TU) developed a method and designed a special installation for determining the adhesive strength to ice of various coatings. To conduct tests to determine the adhesive strength to ice, a special nozzle was developed and manufactured-a cup and steel rods on which the test paint is applied and subjected to freezing in the freezer up to –18 oC. This method allows to determine the physical value of the adhesive strength to the ice in MPa.
The following coatings were selected as test samples: organosilicon-based coating, organosilicon-based coating with the introduction of Foraflex fluoroplastic additive, organosilicon-based coating with the introduction of glass microspheres, epoxy-based coating, silosane-based coating, fluoroplastics-based coating, pure metal (steel 3).
The results were processed on a computer using a special program for numerical data analysis and scientific graphics — Origin. It is established that the most effective anti-icing coatings are coatings based on organosilicon and fluoropolymers, which have an adhesion to ice of 4–6 MPa.
Keywords: organosilicon resins, adhesion, anti-icing coatings.

19 The effectiveness of hydrophobic coatings in protecting oak wood surfaces during accelerated aging
32 The role of moisture in the destruction of coatings on wood

TINTING AND COLORIMETRY
40 Contribution to the global digital transformation

EXPERT VIEW
28 Problems of ensuring the safety of coatings on the Russian market — PhD Fedotov S. I., PhD Evplonova E. S., Rozhkova A. A.

EVENTS
25 Who is the endman? — Andrutskaya O. M.
35 Creating wood coatings online

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CONTENTS

4, NEWS

EXPERT VIEW

12 Changes are coming

36 How COVID-19 affected mergers and acquisitions

RAW MATERIALS. INTERMEDIATES AND PRODUCTS

16 Carbon Black ASAHI CARBON Co now in Russia

26 When the film thickness does not determine the leveling — Vennhoff Kerstin
Abstract:
A new rheological additive has been developed to produce thick layers of self-leveling, water-resistant, highly transparent coatings. The behavior of the additive under different rheological profiles of the system is considered: newtonian, pseudoplastic, and thixotropic.The stages of the production process that are optimal for the introduction of the additive and shear force necessary for the introduction of the rheology modifier are determined.
Were tested the sag resistance, the transparency of the coating, water resistance, the ability to be applied in different ways: by brush, roller, airless spray.
Keywords: rheology, associative thickeners, shear rate, thixotropy.


32 LUMIFLON™ — fluoropolymer for high lifetime finish coatings

38 What you need to know about pearl pigments — Nikitina S., Demenok A.

ECOLOGY AND RESOURCE EFFICIENCY

20 Coatings with low frictional coefficient for systems coating-liquid — PhD Kaverinsky V. S., Kaverinsky D. V.

ECONOMICS AND STATISTICS

30 Fluctuations on the TiO2 market

DISCUSSION CLUB

34 Raw material prices significantly increase the pressure on paint manufacturers

PRODUCTS AND RECEARCH

46 Application of thermal analysis methods for optimization of stoving technique in the enameled wire manufacture process — Doctor of Technical Sciences Popova E. I., PhD in chemistry Karezin K. I.,Doctor of Technical Sciences Sokovishin A. V., PhD in chemistry Fedotov S. A., PhD in engineering Nevskiy R. E., PhD in engineering Chumakov M. I., Doctor of Technical Sciences Babkin O. E.
Abstract:
In this work test method assigning glass transition temperatures of enamel using differential scanning calorimetry without prior removal from the wire is described for the first time. The experimental conditions are selected, test method applicability limits are determined. Using received values of glass transition temperature as a marker of stoving mode for polyesterimide enamel of PEEA-155 wire we were capable to distinguish among the others the mode, ensuring sufficient mechanical strength, high elasticity and dielectric strength of polyesterimide enamel without loss of capability to be washed off by mixed organic solvents.
Keywords: glass transition temperature, thermal analysis, enamel wire.


EVENTS

43 Сooperation began to take shape — Andrutskaya O. M.

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CONTENTS

4, 46 NEWS

ECONOMICS AND STATISTICS
8 New additives for aquaeous and non-aquaeous coating systems

EXPERT VIEW
10 Expanding the boundaries of water-based materials

COMPANY’S PORTRAIT
12 New horizons of NOVAROLL: we are ready to cooperate! Dispersion NOVADISP

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
15 DESMODUR ® aliphatic polyisocyanates for elastic coatings: new features —Golling Florian, Eroma Boris, Verboom Dik, Tasich Srba
Abstract:
New specialized aliphatic polyisocyanates that allow varying the physical, mechanical and paint properties of coatings, as well as meeting the stricter requirements of industrial safety (regulation of the emission of volatile organic compounds( VOC), limiting the content of residual monomers) are considered. The series includes products with increased functionality (for faster curing and better chemical resistance) and low viscosity (for compositions with low or zero VOC content), as well as products that allow you to increase the flexibility and elasticity of the final coatings, positively affecting properties such as scratch resistance, abrasive wear and impact. This series includes allophonates of hexamethylene diisocyanate, prepolymers based on hexamethylene diisocyanate and isoforone diisocyanate with polyesters or polycarbonate diols as skeletal molecules. Tests of hardness (Shore A, D), elasticity, tensile stress, and elongation showed the superiority of new products over traditional ones.
Keywords: aliphatic polyisocyanate, coatings, hexamethylen-diisocyanate, isophoron-diisocyanate.

21 SILICONI COMMERCIALE SPA — the leading manufacturer of defoamers and deaerators — Zorbas Theodorus, Platitsyn Kirill
24 Carbon pigments and fillers for electroconducting systems — PhD Kaverinsky V. S., Kaverinsky D. V.

DISCUSSION CLUB
18 In search of consensus — Andrutskaya O. M.

TECHNOLOGIES AND EQUIPMENT
34 Algorithm of designing of the technological line for paint application— graduate Sharapova I. I., PhD, Professor Menshikov V. V., PhD, associate Professor Bogomolov B. B., PhD, associate Professor Boldyrev V. S., Kuznetsov S. V.
Abstract:
The article presents the analysis and main approaches to the choice of coatings and their application technology. A logical model of the life cycle of a coating system is presented. The key features of developing an algorithm for designing a technological line for applying paints with the possibility of choosing a coating system taking into account the operational, technological and economic characteristics of the project are considered. The algorithm developed by the authors was tested during the project on the development and implementation of a coating system for the protection of metal structures operated in cold (temperature limits from –60 °C to +40 °C) and Arctic climate.
Keywords: coatings, paint technologies, corrosion protection, algorithm, modeling, production organization, process line design, business process.


EVENTS
28 CHEMISTRY in gloves

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43 INDEX OF ARTICLES PUBLISHED IN 2020

CONTENTS

4, 45 NEWS

TECHNOLOGIES AND EQUIPMENT
8 Dry grinding in a continuous and periodic process
14 Recommendations for grinding

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
11 Polymer dispersing and wetting additives

22 INSQIN®: a new era in textile coating technology — Dr. Michaelis Thomas, Eroma Boris
Abstract:
A new technology for manufacturing textile coatings based on water-based polyurethane dispersions (PUD) INSQIN® has been developed.
In the new process, the effect of resembling natural leather is achieved by applying a layer of stabilized micro-foam obtained from PUD to the prepared base and then drying it in a tunnel oven. It completely eliminates the use of organic solvents, reduces water consumption by 95% and reduces energy consumption by 50% during production.
The technology provides a previously unattainable level of environmental safety and occupational health in the production and operation of cutting-edge materials for automotive interiors, shoes, clothing, accessories and other applications.
Keywords: polyurethane dispersions, artificial leather, textile coatings.

35 Pigments and fillers for conductive systems. Metal pigments — PhD Kaverinsky V. S., Kaverinsky D. V.
Abstract:
Coatings with certain electrical characteristics are considered: liquid coatings intended for application in an electrostatic field, powder coatings for application in a high-voltage electric field, and coatings for application by electrodeposition methods. It is believed that the optimum electrical and physical-mechanical properties of electrically conductive coatings are achieved when two interpenetrating phases occur in the coating: a continuous grid of an electrically conductive filler and a grid of a film-forming agent oriented in it. Electrically conductive pigments and fillers allow electricity to pass through the coating or dissipate. Powders of silver, gold, copper, aluminum, tin, iron, and nickel are used in conductive coatings.
Keywords: metal pigments, specific volume electrical resistance, polymer compositions.


INTERVIEW
18 «Delivery of quality equipment is our main customer support program...»

PRODUCTS AND RESEARCH
28 Experimental and calculated dependences of packing density in mixtures of fillers of various composition. Part 4 — Furman N. N.
Abstract:
The dependence of the packing density of mixtures of fillers with different grain sizes at their different mass ratios has been studied. The regularities of the growth of the package volume during its filling have been revealed. A method for determining the point of maximum compaction of the mixture is proposed. Approaches to predicting and calculating the volume and density of packages of mixtures of fillers for paints and varnishes based on experimental data are proposed.
Keywords: discrete topology, the packing density, the volume of packaging, fillers, the degree of filling of the package.


STANDARTIZATION AND METROLOGY
38 Modern methods and standards for testing materials for fireproof properties.
Part 3 — PhD Pavlovich A. V., doctor of technical Sciences Drinberg A. S., Okhrimenko A. G.

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CONTENTS

4, 51 NEWS

ECONOMICS AND STATISTICS
8 Oil-gas industry — important consumer of coatings — PhD Kaverinsky V. S., Kaverinsky D. V.

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
16 Anti-microbial coatings and COVID pandemic

PRODUCTS AND RESEARCH
18 Highest Matting Agent Loading with Outstanding Viscosity Reduction in 100%-UV Coatings. Utopia or reality? — Örü Selma, PhD Giebelhaus Irina
Abstract:
Based on special hyperbranched polymers, new wetting and dispersing additives have been developed for solvent-free UV-curable coatings matted with silica. Thanks to specially selected pigment affinity groups, the hyperbranched polymer is adsorbed on the surface of the matting additive, keeps the particles separated and prevents flocculation of the matting additive particles. In the tests conducted, the new developments demonstrate outstanding viscosity reduction properties combined with Newtonian flow, offering remarkable advantages for the development and application of matte solvent-free UV-curable lacquers.
Keywords: UV-curable coatings, hyperbranched polymers, matting additives.

28 Method for testing anti-corrosion and anti — fouling coatings with a long service life — PhD Boldyrev V. S., doctor of technical Sciences Menshikov V. V., Ildarkhanova F. I., PhD Averina Yu. M., Stepankov E. K.
Abstract:
The analysis of existing methods for evaluating anticorrosive and antifouling coatings is carried out. A set of test methods was proposed, taking into account domestic standards and international ISO standards. The presented test method allows to make scientifically justified tests of both commercially produced and newly developed coatings for the protection of the underwater part of ships, hydraulic structures, bridges and other metal and concrete structures operated under water and subject to biofouling.
Keywords: marine coatings, anti-corrosion properties, anti-fouling properties, accelerated testing.

33 Coatings for shuttle BURAN — doctor of technical Sciences E. K. Kondrashov
Abstract:
The main requirements to be met by the paint coatings of the RSP Buran were formulated. The properties of the EP-0214 primer, which provides reliable fixing of heat-protective tiles on the outer surface of the Buran, are considered in more detail. The list of almost all coatings used for RSP and the properties of KO-5229 and VE-50E enamels developed specifically for Buran is given.
Keywords: RSPBuran, heat-protective tile, epoxy-rubber primer, cyclic testing.


TINTING TECHNOLOGIES AND COLORIMETRY
26 New measurement technology for evaluating painted car body surfaces

POINT OF VIEW
40 Continuous process as a perspective of the dispersion process — PhD Kaverinsky V. S., Kaverinsky D. V.

STANDARTIZATION AND METROLOGY
18 Modern methods and standards for testing materials for fireproof properties. Part 2 — PhD Pavlovich A. V., Pavlenko D. F., doctor of technical Sciences Drinberg A. S., Okhrimenko A. G.

EVENTS
14 This year, you can visit CHINACOAT-2020 both online and offline!

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CONTENTS

4, 51 NEWS

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
10 Novel components for fire-resisting and fire-retarding coatings

PRODUCTS AND RESEARCH
14 More adhesion, more protection. New concept of adhesion promoters for anti-corrosion protection — Muth Martin

26 Experimental and calculated dependences of packing density in mixtures of fillers of various composition. Part III — Furman N. N.
Abstract:
The dependence of the packing density of mixtures of fillers with different grain sizes at different mass ratios is studied. The regularities of the growth of the volume of packaging when it is filled are revealed. Approaches to forecasting and calculating the volume and density of packaging mixtures of paint and varnish fillers based on experimental data are proposed.
Keywords: discrete topology, the packing density, the volume of packaging, fillers, the degree of filling of the package.

33 Influence of humidity and temperature on the service life of the optical fiber polymer shell — doctor of technical Sciences, Professor Babkin O. E., Vlasov M. Yu., Buralkin M. V., PhD, associate Professor Babkina L. A.
Abstract:
Fiber optics can provide maximum speed of information that works in all climatic zones. The lifetime of the optical fibre must be at least 25 years and the protective polymer shell on the fibre must be able to withstand this lifetime. Soil and lacquer compositions have been determined in the work based on the research carried out.
Keywords: optical fiber, light guides, polymer shell.


44 Properties of the ferrite pigment obtained from foundry waste and brucite —Karandashov S. A. , Professor, PhD in Chemistry Stepin S. N. , Holmurodov T. A.
Abstract:
A number of products containing magnesium ferrites are obtained by calcination of mixtures of different compositions of man-made waste of runaway dust containing 70 wt % of iron oxides and natural magnesium hydroxide (brucite). Temperature-time conditions of ferrite pigment production were found. Anticorrosion properties of its aqueous extracts are shown. The range of brucite content in an initial furnace charge at which synthesized pigments are characterized by maximum positive effect on protective properties of alkyd coatings is determined.
Keywords: ferrite pigments, anti-corrosive properties, alkyd coatings.


STANDARTIZATION AND METROLOGY
18 Modern methods and standards for testing materials for fireproof properties. Part 1 — doctor of technical Sciences Drinberg A. S., PhD Pavlovich A. V.
36 Modeling of fire resistance of structures in software complexes, including using fire protection — PhD. Gravit M. V.

ECONOMICS AND STATISTICS
23 Flame protection coatings: market factors, trends

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PRODUCTS AND RESEARCH
10 Protecting both air and steel. Water-borne silane creates heat-resistant low VOC zinc dust primers - Philipp Albert
Abstract:
A water-borne inorganic binder for two-pack zinc dust paints is almost VOC-free and can replace both organic and inorganic solvent-borne binders. Both fast drying shop primers and heavy-duty anticorrosive paints can be formulated. Good corrosion resistance was obtained in salt spray tests.
Keywords: silanes, corrosion resistance, zinc dust.


28 Thicker than water. A new class of rheology additives for water-borne systems - Dominika Bernert, Sylvia Bühne, Kathrin Möllers, René Nagelsdiek
Abstract:
A new class of liquid additives based on polyamide chemistry that can be successfully used to control the rheology of water systems has been developed. Unlike conventional thickeners, these polyamides do not require thermal activation. They are presented as an easy-to-use, low-viscosity solution and do not require any extensive pre-gel production. The molecular structure of this class of additives can be adapted to the intended use. Rheological additives provide good results in many water-based systems. In water-soluble epoxy compositions, the new additives show a pronounced tolerance to the addition of the hardener, i.e. after the addition of the hardener, the viscosity does not fall. Additives not only increase the viscosity, but also control the viscoelastic properties of the coating and can therefore be used to improve the orientation of effective pigments.
Keywords: additives, rheology, thickeners, water-based systems.


38 Water epoxy emulsions stabilized by microparticles of polymers — Ph. D. Shinkareva E.V
Abstract:
The presence of polymer microparticles enhances the stability of aqueous emulsions of epoxy resins during storage. Emulsions stabilized by acrylic-methacrylic aqueous dispersion of the polymer are most stable. Emulsions stabilized by these polymer particles are stored for 24 months without visible signs of separation. Using a test surfactant (sodium oleate), it was found that the degree of adsorption saturation of some industrial water dispersions of polymers and the values of the free energy of adsorption of nonionic emulsifiers by the surface of their microparticles decrease in the series acrylic-methacrylic  polymethylsiloxane  styrene-acrylate  carboxylated butadiene-styrene. It was shown that aqueous dispersions of polymers with an unsaturated surface adsorb nonionic emulsifiers the stronger, the higher their polarity. It has been suggested that the stabilizing effect is associated with heterostabilization of particles of the mixed dispersed phase and the strength of the formed structural framework.
Keywords: epoxy resins, water emulsions, non-ionic emulsifiers.


INTERVIEW
16 Change back

EXPERT VIEW
32 Trends of protective coatings in the next years — Ph. D. Kaverinsky V. S., Kaverinsky D. V.
36 Choosing the right additives

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
19 Silicone emulsion paints: long-lasting decorative coatings with a low volatile content
22 Innovative coatings for mineral surfaces

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4, 48 NEWS

PRODUCTS AND RESEARCH
10 New resins for coatings for plastics — Kazunori Tanaka, Michael Venturini, Michael Scrivner

14 Evaluation of the ability to thicken styrene-acrylic dispersions in the presence of HEUR thickeners — Pavlikova S. M., PhD Anisimova S. V., Titanina T. I., PhD Rogozhin A. E.
Abstract:
Research has shown that the result of thickening styrene-acrylic dispersions in the presence of polyurethane thickeners and the stability of viscosity retention over time is influenced by the composition and properties of the polymer dispersion: the glass transition temperature of the copolymer, the nature of the monomer in the copolymer, the content of a carboxyl-containing monomer, the presence of a water-soluble protective colloid, the amount of non-ionic surfactant, the size of the dispersion particles.
Keywords: styrene-acrylic dispersions, polyurethane thickeners, colloids

20 Studies of aqueous hybrid silicone-acrylic and acrylic-silicone dispersions — Janusz Kozakiewicz, Joanna Trzaskowska, Wojciech Domanowski, Anna Kieplin, Izabela Ofat-Kawalec, Jarosław Przybylski, Monika Woźniak, Dariusz Witwicki, Krystyna Sylwestrzak

26 Stability and structural-rheological properties of water emulsions of epoxy resins — PhD Shinkareva E. V.
Abstract:
The article shows that the most effective emulsifiers for the preparation of aqueous emulsions based on ED-20 resin are Emulsogen LCN-287 and OS-20; Resins NPEL 127, NPEL 128, CHS-EPOXY 520, CHS-EPOXY 530 — Emulsogen LCN-287. The optimal concentration of resins in emulsions is 60 mass. %, emulsifiers — Emulsogen LCN-287 — 1×10–2 mol/l and OS-20 — 5×10–3 mol/l, emulsification temperature of resin ED-20 — 20 °C, NPEL 127, NPEL 128 and CHS-EPOXY 530 — 40 °C; CHS-EPOXY 520 — 50 °C. The method of emulsification of resins ED-20, NPEL 127 and CHS-EPOXY 520 — the method of direct emulsification and phase inversion; NPEL 128 and CHS-EPOXY 530 are phase inversions only. The resulting emulsions are polydisperse (0.1–250 μm, the predominant fraction is 0.1–5 μm) and are characterized by relatively low stability (no more than 7–12 days), and their sedimentation time is 10–20 days. It was shown that the ED-20 resin and H2O–(ED-20) system emulsions are structured non-Newtonian fluid-like systems, the studied resins NPEL 127, NPEL 128, CHS-EPOXY 520, CHS-EPOXY 530 are Newtonian fluids, and emulsions based on them are non-Newtonian. To increase the stability of emulsions, their additional stabilization is necessary.
Keywords: epoxy resins, emulsions, structural and rheological properties


39 Methods of producing microcapsules with functional fillers for paints — Makarov A. V., Skivko P. V., PhD Silaeva A. A., PhD Kvasnikov M. Yu.
Abstract:
In thе paper have studied the principles and developed technologies for producing microcapsules using interfacial polycondensation, suspension polymerization and evaporation of a volatile solvent for the subsequent addition to the paint system. Studies have confirmed the success of the encapsulation of reducing or inhibiting components in the polymer shell.
Keywords: encapsulation, microcapsules, polymethylmethacrylate, benzotriazole


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PRODUCTS AND RESEARCH
10 New approaches in corrosion protection — PhD Kaverinsky V. S., Kaverinsky D. V.

15 New generation of low temperature hardeners for epoxy systems — Shustov R. Yu.
Abstract:
The influence of ‘AraCool’ grades depending on the stoichiometric ratio and the curing temperature on the corrosion resistance and the rate of hardening of the coating are studied. It was found that the deviation from the stoichiometric ratio to the level of 80% is not critical for the coating.
The comparison of ‘AraCool’ brands with phenalkamines and PAA in terms of corrosion resistance is shown. ‘AraCool’ brands, at least, are not inferior to PAA, and in the case of phenalkamine, even surpass it in anti-corrosion properties under the same conditions. A chart has been compiled for the main indicators of ‘AraCool’ products.
Keywords: corrosion resistance, hardeners, epoxy systems.


29 Influence of silicone binder on the process of oxidation of particles of titanium and chromium. Heat resistant coatings based on chrom-titan-resin systems SILRES MSE 100 — PhD Shinkareva E. V., PhD Budeiko N. L., Sycheva O.A.
Abstract:
The article presents the results of studying the process of oxidation of particles of titanium PTOM-1 and chromium PCrX1М and their compositions with silicone resin brand Silres MSE 100. Oxidation of titanium particles begins when temperature reaches 370 °С, chromium — 520 °С whereas in the presence of resin the process their oxidation begins much later: when the temperature reaches 700 °C, a composition of heat-resistant paint is designed to protect metal products from corrosion, which during operation can be in the temperature range from –50 °C to +650 °C.
Keywords: silicone binders, heat-resistant coatings, thermographic studies.

38 Dispersants of the brand Macromer for water dispersion paints — PhD Mikheev S. V., PhD Tarasov V. N., Korotkova N. P., Agafonova K. S., Styunina A. O.
Abstract:
This article presents the dispersants for water-dispersion paints of the brand ‘Macromer’ and the results of research regarding the influence of their structure on the efficiency of the dispersion process, as well as the protective and operational characteristics of paint coatings.
Keywords: dispersants, water-based coatings, stabilization mechanisms.

EXPERT VIEW
20 Long jump

EVENTS
44 INTERLAKOKRASKA-2020 worked ahead of time — Andrutskaya O. M.

INTERVIEW
50 Get into color

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PRODUCTS AND RESEARCH

8 Influence of coating formulation on its mechanical properties and cracking resistance — Podgorski Laurence, De Meijer Mari, Lanvin Jean-Denis

11 Wax emulsions that enhance the properties of wood coatings

16 Influence of the molecular weight of diisocyanates on the thermal stability of fluoropolymer coatings — Doctor of technical Sciences Kondrashov E. K., Ph. D. Haskov M. A., Derikov D. S., Rakova T. M.
Abstract:
The effect of diisocyanates with a molecular weight of 206 and 420 a.u.w. was investigated. On the loss of mass and color change of fluoropolyurethane coatings at a temperature of 200 °C and it is shown that diisocyanate with a molecular weight of 206 a.u.w. It can be used in dark colored fluoropolyurethane coatings, since it allows one to obtain significantly more thermostable coatings than when using diisocyanate with a molecular weight of 420 a.u.w.
Keywords: diisocyanate, molecular weight, polyurethane fluoride, heat resistance.

21 Water emulsions of organosilicon resins. Composite coatings based on them — candidate of technical sciences Shinkareva E. V.
Abstract:
The results of the study of the stability of oil-in-water emulsions of methyl phenylsiloxane and epoxy siloxane resins depending on the emulsification regimes (shaft speed of the dispersing device, dispersion time), the emulsification method, the nature of the resins, the concentration of emulsifier and stabilizer are presented. The structural and rheological properties of individual resins and emulsions based on them are investigated. The composition of water-dispersion paint for the formation of heat-resistant coatings on metal is developed. The results of studies of the physicomechanical properties of coatings are presented.
Keywords: water emulsions, organosilicon resins, heat-resistant coatings.


38 Choice of monofunctional reactive diluent for modification of the epoxy system properties — Akulinicheva A. A., Korotkova N. P., Stunina A. O.
Abstract:
The results of studies of the type of monofunctional aliphatic active diluents influence on the technological properties of epoxy compositions, as well as the strength characteristics and chemical resistance of the cured material are presented.
Keywords: active diluents of epoxy resins, monofunctional aliphatic diluents, glycidyl ether of fatty alcohol C12–C14.


41 Temperature-regulating coating for screens of cryovacuum chambers simulating the conditions of outer space — Ph. D. Mavrutenkov A. A., Komarov M. V.
Abstract:
This article describes the main requirements for temperature-regulating coatings used for cryogenic equipment of vacuum chambers. The analysis of paints and coatings offered by manufacturers is carried out, the results of comparison and testing of coatings with an assessment of the scope of their possible application are presented.
Keywords: temperature-regulating coating, vacuum chamber, solar radiation absorption coefficient, degree of blackness.


45 Glass transition temperature control of uv curing compositions for fiber optic — Gutenev А. А., Doctor of Tech. Sci. Babkin O. E., Vlasov M. Yu., Candidate of Tech. Sci. Aikasheva О. S.
Abstract:
In production of optic fiber a protective polymer shell is used — elastic primer and hard lacquer coating. Some consumption sectors of optic fiber have special requirements for the primer coating, namely, the glass transition temperature must be lower than –70 °С. In this paper, ways to reduce the glass transition temperature of the primer coating are analyzed and dynamic mechanical analysis shows the possibility of reducing this indicator.
Keywords: optical fiber, glass transition temperature, coatings.


EXPERT VIEW
49 About the roughness of paint coatings — Ph.D. Kaverinsky V. S., Kaverinsky D. V.

EVENTS
32 Key components of optimal formulations — Andrutskaya O. M.
37 «Homa sphere-2020»: IX conference of Homa company

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CONTENTS

4, 55 NEWS

ECONOMICS AND STATISTICS
14 Architectural coatings market
34 Situation on the global titanium dioxide market

PRODUCTS AND RESEARC
8 The study of heat resistance of fluoropolyurethane coatings — Doctor of Technical Sciences Kondrashov E. K., PhD Haskov M. A., Derykov D. S., Rakova T. M.
18 Self-cleaning facade coatings — Andaloro A., Mazzucchelli E. S., Lucchini A., Pedeferri M. P.
24 Behavior of sulfonic acid-based corrosion inhibitors in the presence of zinc phosphate. Search for optimal ratios for maximum corrosion resistance of a coating — Shustov R. Yu.

28 Coatings for optical light guides optical fiber systems — Doctor of Technical Sciences, Prof. Babkin O. E., Vlasov M. Yu., Buralkin M. V., Associate Professor Babkina L. A., PhD Aykasheva O. S.
Abstract:
The production of optical fiber was launched in Saransk at «Optical Fiber Systems». The article presents the results of the import substitution program of domestic ultraviolet curing polymer coatings. On the basis of four schemes of protective coating for optical fiber at speeds of 1200–1600 m/min, the optimal coating scheme and formulation of soil and varnish have been determined.
Keywords: optical fiber systems, UV-curable polymers, refractive index.

38 Experimental and calculated dependences of packing density in mixtures of fillers of different compositions. Part 2 — Furman N. N.
Abstract:
The dependence of the packing density of filler mixtures with different grain sizes at their different mass ratios was studied. The range of maximum filling of the package is determined. The regularities of the growth of the packaging volume when filling it were revealed. Approaches to predicting and calculating the packing density of filler mixtures based on experimental data are proposed.
Keywords: discrete topology, packing density, packing volume, fillers, degree of packing filling.


44 Bacteria of the genus Bacillus as a biocide of water-based dyes — Grand PhD in Veterinary sciences, Prof. Neustroev M. P., Neustroev A. I., Grand PhD in Veterinary sciences, Prof. Tarabukina N. P., Neustroeva A. I., PhD in Veterinary sciences Stepanova A. M., PhD in Veterinary sciences Parnikova S. I.
Abstract:
The ability of bacteria Bacillus subtilis TNP-3-DEP (strain RCAM 04759) to inhibit the activity of microscopic fungi of the genera Penicillum sp., Penicillum citrinum, Penicillum purpurogenum and Aspergillus niger, which cause biodegradation of water-borne paints and varnishes, has been established. In a water-borne interior paint with the addition of a bacterial suspension of B. subtilis TNP-3-DEP as a preservative, the growth of microscopic fungi was not observed for 13 months (observation period). In this case, the activity of hydrogen ions, conditional viscosity, hiding power and adhesion in compliance with requirements (TU 2388-002-38694560-2012). In the samples without the addition of a bacterial strain or other biocide, growth of fungi A. niger, Penicillum sp., P. purpurogenum, P. citrinum was observed from the first month of the study, and was recorded at 12 months of observation lysis of paint. Scientific n The large number of studies on the development of an environmentally friendly and safe biocide is confirmed by the patent for the invention of the Russian Federation (No. 2654597, 2018).
Keywords: paint and varnish material, biodegradation, microscopic fungi, Bacillus subtilis, biocide.


SUSTAINABILITY AND RESOURCE EFFICIENCY
49 Norms: 90 or 5000 ppm — two big differences — PhD Kaverinsky V. S.

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CONTENTS

4, 87 NEWS

ANNIVERSARIES
9 60 years with the industry — Andrutskaya O. M.

EVENTS AND FACTS
12 Joint efforts to solve common problems — Timofeev N.

22 On sustainable development of the Paint Quality Association

EXPERT VIEW
18 Why is national globalization of the Russian paint industry important? — Averyanov G. V.

BRANCH MARKETING
25 Market overview of heat resistant organosilicon enamels

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
40 Properties and applications of titanium oxide (IV) — Ph. D. Neelova O. V., Ph. D. Shutov D. G.
Abstract:
A review of the physical and chemical properties of titanium oxide (IV), methods for its industrial production and its main applications is presented. It has been shown that titanium (IV) oxide is widely used as an active filler for polymer composite materials, in particular, silicone compounds intended for the protection and sealing of electronic products. The use of titanium dioxide brand «especially pure» titanium allows one to obtain the necessary technological properties of silicone compositions (viscosity, thixotropy), improve the physical, chemical and mechanical characteristics of cured elastomeric coatings and increase their resistance to high temperatures (250–350 °C), humidity and electrical stresses.
Keywords: titanium dioxide, physical and chemical properties, methods of production, filler, composite materials.

53 Production of resins for coatings in Russia — Galkina Yu. V., Korbush M. K.

64 Modern epoxy technology for liquid and powder paints — Dennissen Tuan A. M., Reztsova A.

80 Import substitution in corrosion protection

COMPANY’S PORTRAIT
14 40 years of environmental protection technology from Bavaria

15 LLC NPP Spectr — 20 years of impeccable work

47 HILONG anti-corrosion coatings

PRODUCTS AND RESEARCH
30 Research of adherence between the varnish decal film and the porous glazed ceramic surface — PhD Papulova G. N., PhD Kvasnikov M. Yu.
Abstract:
Considered types of decal decoratrion. Defined technological features and comparative characteristics. Сonsidered methods of glaze hardening. We describe the compositions of mastic for adhesive increasing of decal film and ceramic surface.
Keywords: ceramic surface, decal, glaze, filmformer, surface hardening, adhesive mastic


33 Multifunctional superwetting agent for coating applications — Vimal Saini, Wolfgang Fuchs, Elke Piron, Carlos Feito, Udo Schonhoff, Frank Abschlag

57 The changes in the indicators of water-dispersion compositions and coatings on their basis after freeze-defrost cycles — Krikotnenko V. S., Kotelnikov D. V., Evdokimov A.V., Sergunenkov B. B.
Abstract:
It was found that during cyclic tests of a number of waterborne paints and adhesives in accordance with GOST R 52020-2003 for frost resistance appearance, (coagulation, delamination) of the compositions does not change, but there is a significant change in the properties of viscosity, hiding power, rinseability of coatings and adhesive ability.
Keywords: latex, paints, frost resistance, adhesive strength, adhesion

74 Experimental and calculated dependences of packing density in mixtures of fillers of different compositions. Part 1 — Furman N. N.
Abstract:
The dependence of the packing density of filler mixtures with different grain sizes at their different mass ratios was studied. The range of maximum filling of the package is determined. The regularities of the growth of the packaging volume when filling it were revealed. Approaches to predicting and calculating the packing density of filler mixtures based on experimental data are proposed.
Keywords: discrete topology, packing density, packing volume, fillers, degree of packing filling.


EVENTS
82 International coatings forum

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CONTENT

4, 54 NEWS

ECONOMICS AND STATISTICS
8 Bio-based coatings: the market is small, but the potential is huge

40 Powder coatings industry in China

42 Market of waterborne coatings

ECOLOGY AND RESOURCE EFFICIENCY
10 Actions to limit lead content in paint

16 Challenges of household hazardous waste

37 New technologies to reduce the carbon footprint in the paint industry

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
11 Using 3M™ glass microspheres in anti-condensate paints — Ruckebush J.-M., Dmitriev A., Hoteev S.
Abstract:
A formulation of anti-condensate paint with values below the COCP using 3M™ S22 microspheres has been developed. A new method for determining the condensation time has been described, by which comparative tests of the sample with microspheres and various types of anti-condensate paints available in the EU market, as well as conventional wall/ceiling paint, have been carried out. The performance of coatings was measured in terms of resistance to condensation as well as physical properties such as dry/wet material density and solid content. Also, using the method of linear regression, modeling of the paint composition and optimization of the mixture, three limit parameters were calculated: rubber, calcium carbonate and glass microspheres 3M S22. It is shown that the use of hollow glass microspheres 3M allows you to create paints with low density and low thermal conductivity, with values below the CVCP. Such paints have excellent strength characteristics and significantly shift the dew point.
Keywords: microspheres, condensation, critical volume concentration of pigment.


22 Phenalkamine hardeners CARDOLITE for epoxides without solvents — Galkina Yu. V.

26 Silane-terminated polyurethanes: Covestro presents an expanded line of DESMOSEAL® S products — Matner M., Baumbach B., Tibes K.,
Eroma B.
Abstract:
The properties of silane-terminated polyurethanes in the compositions of adhesives and sealants are considered and the process of their production is described. The properties of the obtained compositions were studied: film formation time, Shore A hardness, elongation at break, tensile strength, shear strength. It is proved that adhesives and sealants based on Desmoseal S products have a good curing rate and a complex of high physical and mechanical characteristics.
Keywords: polyurethanes, adhesives, sealants.


PRODUCTS AND RESEARCH
17 Reduction of zinc powder content in protective primers due to the inclusion of core pigments with polyaniline shell — Prof. Stepin S. N., PhD Tolstosheeva S. I., Vakhitov T. R.
Abstract:
The possibility of reduction of zinc powder content in the protective primers due to the introduction of core pigment synthesized by oxidative polymerization of aniline in the presence of microtalc is shown. Analysis of the electric capacitance chronograms and the results of chronopotentiometry of the systems comprised of painted steel/electrolyte allows to conclude that the obtained core pigment with the core made of microtalc and the shell made of polyaniline doped with oxyethylidenediphosphonic acid, in addition to its participation in the provision of electric contact between zinc particles, enhances the anti-corrosion properties of the protective primers by means of oxidation-reduction cycle based on reversible polyaniline transition from its emeraldine to leucoemeraldine form.
Keywords: polyaniline, tread primers, zinc powder.

44 New advances in UV-curable tactile coatings

EVENTS
33 Toward to breakthrough technologies through complex scientific and technical projects and development of engineering specialties in chemistry—Petrova T.

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50 INDEX OF ARTICLES PUBLISHED IN 2019

4, 54 NEWS

EXPERT VIEW

10 Problems and trends in the field of flame retardant coatings

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

13 The ways to improve the quality characteristics of fire-retardant intumescent compositions — Korbush M. K.
Abstract:
A starting formulation of a flame retardant intumescent compound based on an epoxy binder cured with a phenalkamine hardener has been developed. Along with high physical and mechanical properties, water and weather resistance, Cardolite hardeners have a high potential for creating effective flame retardants.
Keywords: phenalkamine hardener, epoxy resins, flame retardants.


16 TRIGAL® flame retardants

18 Flame retardants based on magnesia minerals — Kazmina O. V., Mitina N. A., Maltseva E. M.

20 Antistatic epoxy flooring. Part 2 — Pavlov A. V., Ottova P. O., PhD Fedyakova N. V., Zelenskaya A. D.
Abstract:
In this work we studied the possibility of obtaining antistatic epoxy coatings for floors based on industrial epoxy paints and varnishes, DTB-2 aminoalkyl hardener and carbon fibers. The optimal content of carbon fibers in the composition to provide antistatic properties is shown. The effect of coating thickness on antistatic properties at the optimum carbon fiber content was also studied.
Key words: paintwork materials, paintwork coatings, antistatic coating, epoxy materials.


24 Functional coatings: new developments — PhD Kaverinsky V. S., Kaverinsky D. V.

INFORMATION TECHNOLOGIES

27 Information-computing system for designing and construction of industrial painting lines — PhD Bogomolov B. B., Prof., Doctor of Engineering Menshikov V. V., Doctor of Chemical sciences Bolotin B. M., PhD Boldyrev V. S., Elistratkina V. O.
Abstract:
This article describes an example of creating an information and computing system for the design and construction of industrial painting lines. The methodology of infological modeling of databases based on queries is applied. The calculation of the main technological units of the system was made, while it was possible to autonomously calculate any of the three subsystems. All source information and calculation results are stored in a result file recorded on electronic media. An array of the initial data of a specific drying chamber is also saved in the form of a file, which allows not to enter the initial information when recalculating the chamber. Testing of the information-computing system for the design and construction of industrial painting lines was carried out on several variants of painting lines.
Keywords: information and computing systems, painting lines, design, construction, automation, data array analysis, functional information structure, expert systems, calculation of technological units


EVENTS

36 Actual topics of production and application of organosilicate coatings — Andrutskaya O. M.

40 It’s actions that matter. EXPOCENTRE is 60 years old

42 New elements of the exhibition "CHEMISTRY" — Andrutskaya O. M.

48 The Expert technique of RSX has received world acceptance

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4, 56 NEWS

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
9 Organic pigments for industrial coatings — Manoj Bankar

14 New types of phenalcamine hardeners in two-component epoxy coatings — Galkina Yu. V., Korbush M. K.

PRODUCTS AND RESEARCH
18 UV Resistant epoxy system — Shustov R. Yu.

27 New standard for wood coatings. 2K polyurethane water dispersion systems without sacrificing drying time — Dr. Tejada Eva, Dr. Laas Hans-Josef, Dr. Sanchez Berta Vega, Eroma Boris
Abstract:
A novel hybrid hydrophilic polyisocyanate described. Different percentages of TDI in the polymer have been tested. Increasing the amount of aromatic content the reactivity of the polyisocyanate increases, resulting in faster drying and shorter pot-life. However, at the same time, the film transparency is getting worse. An optimized ratio of TDI/HDI leads to products with good reactivity and appearance. Anionic hydrophilization has been proven the most effective type for getting fast drying combined with film transparency and outstanding chemical resistance.
Keywords: polyurethane, polyisocyanate, wood coatings, crosslinkers.


36 Heat-resistant enamels with high reflection and low radiant emittance — Doctor of technical science Kondrashov E. K., Vereninova N. P.
Abstract:
Influence of disperse aluminum fillers of different manufacturing techniques on reflective and radiating characteristics of heat-resistant organic silicon coverings is shown.
Keywords: silicone coatings, fillers, reflection coefficient, radiating coefficient.

42 Influence of kind of amine hardener modified by polyaniline on formation of epoxy coatings — Mag. Pugacheva T. А., PhD Kurbatov V. G., Prof. Indeikin E. A.
Abstract:
The effect of the chemical composition of the amine hardener, modified by polyaniline, on the rheological properties of epoxy compositions is shown. It has been established that the most initial viscosity is characterized by compositions containing polyethylenepolyamine. It has been determined that the polyaniline content has a different effect on the rheological properties of epoxy compositions with different hardeners. It is shown that the chemical composition of the amine hardener modified polyaniline also affects the process of curing epoxy coatings. The greatest depth of the curing process is observed when used the modified triethylentetramine as a hardener.
Keywords: epoxy coating, hardener, polyaniline, curing.


INFORMATION TECHNOLOGIES
22 Great opportunities to create formulations

EVENTS
34 VR/AR for the chemical industry at the exhibition

CHEMISTRY-2019
47 The stars aligned! Awards ceremony of chemical industry leaders took place in Moscow

50 The main purpose of investments are people — Andrutskaya O. M.

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4, 45 NEWS

SUSTAINABILITY AND RESOURCE EFFICIENCY
9 New approaches for alkyd resins — PhD Kaverinsky V. S., Kaverinsky D. V.

EXPERT VIEW
16 Problems of the of epoxy resins market

RAW MATERIALS. INTERMEDIATES AND PRODUCTS
18 Russian-made modified resins brand ATTALATE — Galkina Yu. V., Korbush M. K.
Abstract:
The properties of acrylic copolymer for road marking are considered. Tests of the coatings resistance to abrasion by the method of a rotating abrasive wheel were carried out. It is noted that the coatings are characterized by rapid drying, color stability, wear and moisture resistance, have internal plasticization, which allows to achieve optimal ratios between flexibility and hardness. Unlike other air-drying binders, this resin provides coatings with high hardness and low solvent content.
The properties of alkyd resin modified by petroleum polymer resin (PPR) were also investigated. Testing showed that the introduction of PPR contributed to the improvement of water resistance of the priming enamel, while the hardness of the coating and other physical and mechanical characteristics has not changed.
Keywords: acrylic copolymers, alkyd resins, petroleum polymer resins.


25 New multi-functional additive

28 Modification of bitumen as binder — Ambartsumov D. A., Alekseeva S. V., Aksenov A. S., Candidate of Engineering Sciences Merezhko D. V., Doctor of Engineering Sciences, Professor, Mnatsakanov S. S.
Abstract:
Of all the possible polymer-modifications of bitumen were described by a new version of the strengthening of bituminous oligomeric condensation system its polar fractions using carbon nanobodies.
Keywords: bitumen, carbon nanobodies, fullerene.


SAFETY
22 About the electrical conductivity of flammable and explosive liquids — Amy Helen Rigby

PRODUCTS AND RESEARCH
39 The effect of silanes on corrosion and physical-mechanical parameters of epoxy primer — Shustov R. Yu.
Abstract:
The influence of glycidoxypropyltrimethoxysilane on anticorrosive properties of epoxy resin was investigated. Samples with different silane content were placed in a salt fog chamber for 700 hours. It is found that the concentration of 1.8% silane gives a significant reduction in the degree of corrosion. The concentration of 0.75% did not have a significant impact on the anticorrosion properties.
Tests to determine adhesion by the pull-off method and elasticity of the coating by Eriksen were carried out. It was found that there is a direct dependence of these parameters from the concentration of silane: the more silane, the higher the adhesion and elasticity.
Keywords: silanes, adhesion promoters, corrosion, epoxy resins.


EVENTS
35 Chemists discussed problems of introduction of energyefficient polymeric materials — Andrutskaya O. M.

38 CHINACOAT–2019 — always a great platform where global industry meets!

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4, 55 NEWS

EXPERT VIEW
10 Does the state develop the national paint industry? — Averyanov G. V.

INTERVIEW
16 Domestic printing inks: to be or not to be?

METHODS OF TESTING
23 Methodology of control the colour consistency of pigments by SUDARSHAN in coatings. Starting formulations of colours

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
28 Effective solutions use of blanс fixe in formulations of alkyd coatings — Buziner L. Yu., Galkina Yu. V., Korbush M. K.

31 The advantages of controlled viscosity at all stages of the technological cycle — Sascha Kockoth, Marina Gajewiak, Verena Boeckmann

40 Antistatic epoxy flooring. Part 1. — Pavlov A. V., Ottova P. O., PhD Fedyakova N. V., Zelenskaya A. D.
Abstract:
This paper is devoted to the creation of antistatic epoxy coatings for concrete floors. As a base it is proposed to use epoxy commercially produced сoating and an amino-acrylic hardener DTB-2 as a hardener. To impart antistatic properties to the coating, the possibility of introducing nanoparticles is investigated: single-layer and multi-layer nanotubes. It is shown that the introduction of nanotubes in such compositions is impractical.
Keywords: paintwork materials, paintwork coatings, antistatic coating, epoxy materials.


PRODUCTS AND RESEARCH
26 Optimization of optical properties of metallic coatings by wax based rheological additives — Udo Schonhoff, Frank Abschlag

36 The development of coatings with reduced flammability based on vinylated alkyd resins for shipbuilding — Nevzorov G. N., Tarasova I. N., PhD Drinberg A. S., Doctor of chemistry, professor Mashlakowskyi L. N., Doctor of chemistry Garabadgiu A. V., Nedvedskiy G. R., PhD Khomko E. V., Ivanov L. M., PhD Sizov E. A., PhD Vasilyeva E. I.
Abstract:
Comparative fire tests of coatings containing various flame retardants: aluminum hydroxide, magnesium hydroxide, and zinc borate have been carried out. Comparative physicomechanical and fire tests of various film formers: vinyl alkyd oligomer, organic silicon oligomer, silicone-modified resin were carried out. The best flame retardant for such coatings is zinc borate. To obtain a lower flammability coating — 6% zinc borate is sufficient. Cost-effective use of a mixture of flame retardants: aluminum hydroxide and zinc borate, in a ratio of 1:1. Tests on the physicomechanical properties showed that the vinyl alkyd oligomer has the best performance. On the basis of the conducted research, the marine enamel of flame retardants RK-Marine 2180 (TU 20.30.12-349-49404743-2018) was developed.
Keywords: low flammability coatings (LFC), flame retardants, flame attenuation length, aluminum hydroxide, magnesium hydroxide, zinc borate, vinyl alkyd oligomer, silicon organic oligomer, silicone-modified resin.

50 Petropolymerıc resins obtaıned on the basıs of oxyacıds from dıesel fractıon — prof. Ibragimova М. J., Doctor of Technical Science Amirov F. А., Salimova S. E., PhD in chemistry Pashayeva Z. N., doctor of chemistry Efendiyeva L. M., Baghirova B. F.
Abstract:
The synthesis of petropolymeric pitch — phenoformalite — on the basis of light gasoil of catalytic cracking of phenol and formaldehyde with the using a new ionic-liquid catalyst morpholine hydrogen sulfate was carried out. The influence of various factors — the ratios of the initial components, the concentration of the catalyst, and the duration of the reaction to polycondensation process — was investigated and the optimal conditions for the synthesis of the reactive petropolymeric pitch were determined. The conditions of hardening of the synthesized pitch were investigated and the possibility of its application as a bonding component in the composition of film-forming and organomineral compositions is shown.
Keywords: petroleum resin, oxyacıds, polycondensation, diesel fraction, dearomatization.


ECONOMICS AND STATISTICS
44 Manufacture of coatings in Uzbekistan and plans for the future

TECHNOLOGIES AND EQUIPMENT
46 Coloring of products from expanded polystyrene — Golubev A. N., Zefirov V. L.
Abstract:
Being considered the question of protective coating for products polystyrene. Water dispersion primers and paints have been selected and tested. It has been established that when using a water-dispersive primer «Akrokor-V», it is possible to paint parts from low density polystyrene foam with traditional enamels containing organic solvents.
Keywords: polystyrene foam, water-dispersion materials, climatic tests.


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4, 45 NEWS

EXPERT VIEW
10 The main factors for anti-corrosive protection

ECONOMICS AND STATISTICS
14 The market for corrosion-resistant materials

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
18 New solutions for stable quality of finishing coatings — Galkina Yu. V.
Abstract:
The formulations of light-resistant two-component (2K) polyurethane (PU) systems for metal using acrylic and polyester resins and aliphatic polyisocyanates were developed. We investigated the properties of self-healing lacquer based on polyester resin Synthoester TH 2844 (70% solution, ОН is 6.0%) and isocyanate Attonate AL 3600. The effect of self-healing was tested by wiping with a sponge with a load (1 and 4 kg) and checking the residual gloss of the coating. It is shown that after 2 hours of testing at a temperature of 60 °C, no scratches were observed, the coating is self-repaired, the gloss remains the same due to the resin with a high density of crosslinking and polyisocyanate of the GDI-trimer type.
Keywords: polyesters, isocyanates, self-healing coatings.


METHODS OF TESTING
22 Climatic tests of fluoroplastic-epoxy coating in the climate conditions of the USA — Pavlov A. V., Ph.D. Andreeva N. P., Ph.D. Merkulova Yu. I., Kozlova A. A.
Abstract:
This paper discusses the climatic tests of a paint coating based on fluoroplast-epoxy coating of grade VE-46 and organosilicon amine. Exposure of samples was carried out at two climatic sites in the USA: Florida Station (subtropical climate) and Arizona Station (desert hot very dry climate) during 1 year. The coating shows high adhesion strength after the completion of the exposure, decorative characteristics change more intensively in the conditions of the tropical climate of Florida.
Keywords: paint materials, coatings, climatic tests.


DISCUSSION CLUB
26 «Quality is moral category ...» — Ph.D. Kaverinsky V. S.

EVENTS AND FACTS
30 Stages of formation and development of paint production in Russia — doctor of technical Sciences, Professor Yakovlev A. D.

EVENTS
39 EUROPEAN COATINGS SHOW once again breaking records — Andrutskaya O. M.

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