Russian Coatings Journal

11/2017
11/2017
CONTENTS

4, 46 NEWS

ECONOMICS AND STATISTICS

10 Situation at European coatings market

PHYSICO-CHEMICAL RESEARCH

12 The choice of dispersant using the parameters solubility by Hansen

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

15 Driers brand ATTDRY for alkyd coatings — Ju. V. Galkina
A wide range of alkyd resins, one metal and combination driers were considered. Using different combinations of resins and driers were developed protective coating and after drying were tested. Found that primers and enamels have high protective properties and are recommended for painting
various metal structures.
Keywords: alkyds, drying agents, protective coatings

20 ALTIRIS — titanium dioxide by HUNTSMAN PIGMENTS & ADDITIVES (VENATOR) for special purpose — L. Yu. Businer
Offered a new brand of titanium dioxide to create a heat reflective coating instead of pigments named cool colors. Investigations of particle size
and distribution for very high refl ectance of solar radiation in the infrared range in comparison with pigment titanium dioxide were carried out. In addition to excellent reflective properties, the new pigments extend the life of coatings as they are much more resistant to photochemical degradation.
Keywords: titanium dioxide, reducing power, heatreflecting coating

POINT OF VIEW

18 Silicone fluids are the most preferred slip additive to meet product durability requirements

AUTOMATION

22 Test track for coatings

TECHNOLOGIES AND EQUIPMENT

26 The new technology of cleaning equipment in the paint industry — Ph.D. V. S. Kaverinsky, D. V. Kaverinsky

EVENTS

28 It was smooth on paper... — O. M. Andrutskaya

METHODS OF TESTING

30 Topological method of calculating the composition of polydisperse mixtures of fillers and forecasting the properties for decorative
finishing — N. N. Furman
With the help of topological methods, the packing density and the optimal composition of compacted polydisperse mixtures consisting of several grades of micromaramor with different average particle diameters are calculated. A formula is proposedfor calculating the critical volume concentration of pigments and fillers. A formula is proposed for calculating the volumetric concentration of pigments with the minimum possible amount of binder. A method for calculating the specific surface area of the filler is proposed. The influence of the packing density, the specific surface of the filler and the size of the binder micelles on the magnitude of the critical volumetric concentration of pigments and fi llersin paint and decorative materials is shown.
Keywords: specifi c surface area, the pigment critical volume concentration, the packing density

PRODUCTS AND RESEARCH

38 Innovation ways for designing new color and optical effect — Ph.D.V. S. Kaverinsky, D. V. Kaverinsky

43 YOUR NAVIGATOR


10/2017
10/2017
CONTENT

4, 55 NEWS

ECONOMICS AND STATISTICS

10 Analysis of the Russian market of fire retardant paints for steel structures in 2012–2016. Forecast until 2025 — Ph. D. Yulia Kislova

24 The European coatings market in 2017

POINT OF VIEW

17 Problem of coatings safety must be solved by joint efforts — Ph.D. V. S. Kaverinsky

48 The staff problems in industry — G. V. Averyanov

PACKAGING

20 Innovation vs classics: the transport of liquid chemicals in drums and IBC-containers

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

22 Resins for the chemically resistant coatings — Yu. V. Galkina

36 New industrial coating materials — academician, Professor, Ph. D. O. L. Figovsky, academician, Professor, Ph. D. P. G. Kudryavtsev,
A. D. Leykin, Ph. D. L. D. Shapovalov, Ph. D. M. Ya. Ioelovich

A number of modern coating materials for various purposes, developed at Polymate Ltd. — INRC, are considered. Hybrid polymer non-isocyanate urethane binders for paints and floorings are successfully used in industrial and civil construction. New materials have a high complex of mechanical and physical-chemical properties. They do not contain hazardous components and volatile solvents. Eco-friendly biodegradable compositions of protective coatings for cellulose-based packaging materials have been developed. Barrier properties of coatings are similar to those of conventional synthetic polymers, and the resulting composite products are subject to recycling. At the stage of intensive development are thermal and fireproof coatings based on polymer-silicate composite materials.

Keywords: nonisocyanate polyurethanes, biodegradable materials, polymer silicates

PRODUCTS AND RESEARCH

25 Barrier against rust by pure, platy talc — Veli Kilpeläinen

The talc grades with diff erent composition, particle shape and particle size distribution were studied to find out their anti-corrosion performance. The results shows that pure, platy talcs (Finntalc M40 and M65) gives better barrier properties (mainly EIS results) compared with impure or blocky talcs (magnesite rich and blocky talcs). The corrosion performance with pure, platy talcs without any anticorrosion pigments give already acceptable results in corrosion protection for the C5-M climate. The blocky or micro-crystalline talc are worse in that respect. Pure, platy, de-dusted talc (Finntalc M40) is overall a very suitable extender for corrosion protective coatings under severe conditions line C5-M. The optimum PVC-level with this talc is 40 vol. % in formulation without anticorrosive pigments.

Keywords: corrosion, talc, electrochemical impedance spectroscopy

30 Leveraging surfactant structure-property relationships to address emerging needs in coatings — Christine Louis, K. Michael Peck

The investigation and product development discussed in this paper demonstrate that surfactant performance can vary significant in formulated systems. There are strong indications that the variation is related to the partitioning of a surfactant to the different interfaces in a formulation and is attributable to the surfactant chemistry itself. A number of products are tailored for activity at select interfaces, whether codispersants for the pigment surface or coalescing surfactants to the latex particle. This approach to optimisation can be applied to general surfactants as well and is particularly eff ective in aqueous pigmented formulations.

Keywords: surfactants, dispersants, coalescents

AUTOMATION
41 Quality Control in formulating and automated systems — I. V. Tretyakov

INTERVIEW
44 Driver of economic growth, or What will be the main topic of discussion at the V Moscow chemical forum?

EVENTS
46 RUCOLOR–2017: focus on major problems in the industry — O. M. Andrutskaya

52 YOUR NAVIGATOR
9/2017
9/2017
CONTENT

4, 47 NEWS

EVENTS AND FACTS

9 The principles of cooperation at creating new coatings — Ph.D. V. S. Kaverinsky, D. V. Kaverinsky

ECONOMICS AND STATISTICS

13 Outstripping growth of direct-to-metal coatings

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

17 New raw materials for corrosion-resistant coatings (review)

PRODUCTS AND RESEARCH

24 Possible ways to improve technological and physical-mechanical properties of zinc-rich primers — A. V. Pavlov, E. A. Miloradova, I. V. Garustovich, Ph.D. O. N. Shishilov, Ph.D. V. E. Subbotin, A. Yu. Shchepetova, T. V. Yakovenko

The paper shows possible ways of modification of the consist of the domestic zinc rich paint composition, namely the decrease of the drying time and the improvement of the physical and mechanical characteristics of the industrial zincrich coating. With the help of Mannich bases the possibility of reducing the drying time of the domestic zinс rich coating was shown. The physicomechanical characteristics of the domestic zinc rich coating with the help of adhesion promoters have been improved, and the low efficiency of aluminum oxide nanofibers as modifiers of the physicomechanical properties for this coating has been demonstrated.
Keywords: zinc-protective primers, zinc-rich paint and varnish materials, epoxy coatings.

29 Wetting and dispersing additives. Past and future challenges — Dr. Horst M. Sulzbach, Dr. Michael Bessel, Janos Hajas

New polymerization techniques (e.g. group transfer polymerization) that provide access to tailor-made, highly effective block copolymer
additives with superior performance were considered. This article presents a short overview of the wetting and dispersing process, the development of different additives over time and more recent developments.
Keywords: additives, carbon black, flocculation, stabilization.

PHYSICO-CHEMICAL RESEARCH

23 Experience in operating system for corrosion rate measurement «MONICOR-2M», set in the framework of the national research university Kazan State Technical University — N. I. Mukatdisov, A. R. Farkhutdinova, Ph.D. A. A. Elpidinski

The article deals with methods of protective action appraisals of the corrosion inhibitors applied in the oil and gas industry. Basis of these
methods and equipments on which tests are carried out were learnt . Following the results of an appraisal of experimental data it was established that results on the corrosion speed received by two different assessment methods, may differ significantly. On the basis of a vailable data assumptions of the reasons of these divergences were made.
Keywords: oil, water, corrosion, protection, inhibitor.

NANOTECHNOLOGY

20 A barrier against corrosion

39 Synthesis and application of nanoparticles of manganese dioxide in coatings for protection of rolled metal — Ph.D. V. E. Katnov, P. V. Grishin, R. R. Katnova, Ph.D., prof. S. N. Stepin

The influence of nanoparticles of manganese dioxide on the properties of transparent coatings used in the technology of roll application. The
possibility of using nanoparticles as a highly effective anti-corrosive additives.
Keywords: nanoparticles, corrosion, coil-coating.

44 YOUR NAVIGATOR
7-8/2017
7-8/2017
CONTENT

4, 53 NEWS

ECONOMICS AND STATISTICS
13 Interation between coating industry and Russia’s government

TINTING TECHNOLOGIES. COLORIMETRY
16 Past and Future of Universal Colorants in Coatings — Frank Kleinsteinberg

20 Software for points of sale (POS) — Sergey Begunov

22 Color measurement of liquid automotive paints

38 Hidden influence. How the color of the primer helps to reveal the potential of the base color paint

EQUIPMENT
24 Service program of COROB company

PRODUCTS AND RESEARCH
29 Giving dirt the brush-off. Easy-to-clean properties now available for epoxy resin systems — Majdi Al-Masri, Wolfgang Griesel, Lin Xie

34 Use of sphenite ores in technology of titanium compounds — Ph. D. (Engineering) E. S. Shchukina, Yu. G. Kiselev, Dr. Sc. (Engineering)
L. G. Gerasimova

44 The research of correlation of the physico-chemical characteristics and structure of CF-oligomers on paint coating properties for ceramic
surfaces — Ph. D. G. N. Papulova

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
39 Protective coatings based on fluorinated polymers — Dr. Sc. A. S. Drinberg, Dr. Sc. V. A. Karpov, A. G. Okhrimenko

SUSTAINABILITY AND RESOURCE EFFICIENCY

48 Future of water-borne coatings under threat

EVENTS
26 New features of effect pigments — O. M. Andrutskaya

50 YOUR NAVIGATOR
6/2017
6/2017
CONTENT

4, 55 NEWS

ECONOMICS AND STATISTICS

9 Water-dispersible paints: optimistic or pessimistic forecast and reality

INTERVIEW

8 Effective or bogus?

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

12 EPS® 572 — new modifed acrylic dispersion for special architectural coatings — Massimo Longoni, David Greener

16 Passive fre protection for hydrocarbon fre — D. A. Dybal, Ph. D. O. N. Shishilov, I. V. Garustovich

20 Intumescent сoatings: the latest developments in truly functional coatings that save lives — Christophe Baude, Maurille Sécher, Cécile Fonteneau, Dr. Alan Fream, Roman Zhukov
In recent years, thin flm intumescent coatings have become the preferred choice for the protection of structural steel and have enjoyed signifcant growth on a global basis. They provide cost-effective passive fire protection to structural steel, while maintaining the aesthetic qualities of the steel, a quality in increasing demand by architects and engineers. However, due to the ever increasing complexity of building design, the sophistication of the design and application of intumescent coatings has also increased.This article gives an overview of the current state of the
thin flm intumescent coatings market, particularly noting progress in the water-based sector, and improvements in water sensitivity, the main weakness of waterborne intumescents.
Keywords: fre retardant coating, water resistance, vinyl acetate copolymers, styrene-acrylate.

28 New components for the formulations of flame retardant materials

30 Binder for thermal and chemically resistant materials — J. V. Galkina

32 Flame retardant materials of LTD “Teplochim” —L. I. Nateikina, E. A. Shikhaliyev

40 Thermo-radiation stable enamel KO-864, on the basis of domestic raw materials — I. N. Tarasova, A. A. Denisov, Ph. D. A. S. Drinberg, I. G. Lakeev, A. Yu. Gerwart
The peculiarities of radiation resistance of various polymers are considered. Studies of the resistance of commercially available resins to prolonged exposure to temperature. Fixed the most effective curing agents for organosilicon resins. Were made tests of the developed
coatings to resistance to neutron radiation, resistance to deactivated and fire testing, determine the forecasted service life. Developed all necessary documentation for the industrial production of thermo-radiation stable enamel KO-864.
Keywords: thermal stability, radiation resistance, absorbed dose, neutron radiation, gray, fluence, decontamination

PRODUCTS AND RESEARCH

36 The study of the effect of the ceramic pigment in the composition of the highly flled paint material on the physico-chemical properties of coatings on ceramic surfaces — Ph. D. G. N. Papulova
The influence of chemical composition of ceramic pigment and its amount in the composition of the highly flled coatings on the physico-chemical properties of coatings on ceramic surfaces in consideration with acid-base properties of fllers and the values of the aluminosilicate module flled with pigmented phase was study. It was found that the use of fllers with M<2 in the composition of the highly flled coatings of different colors reduces the interval M (1.35–2.17), allows to regulate the acid-base surface properties of pigments and to increase the adsorption interaction of carbamide-formaldehyde oligomers with the surface of the pigments and fllers.
Keywords: aluminosilicate module, adsorption equilibrium, carbamide-formaldehyde oligomers

43 A study of the process of obtaining printing inks based on disperse paste — I. A. Antropova, K. E. Merkulov, prof. V. V. Menshikov, R. A. Sandu
Some properties of the printing paints received on the basis of disperse pastes have been considered. Influence of various percentage ratio of components on properties is studied.
Keywords: dispergation, disperse paste, printing ink

EVENTS

48 A new record of the exhibition EUROPEAN COATINGS SHOW — O. M. Andrutskaya

53 YOUR NAVIGATOR
5/2017
5/2017
CONTENT

4, 47 NEWS

ECONOMICS AND STATISTICS

8 The market of paints and varnishes for wood

10 Tasks of the Belarusian market — to develop paint and varnish production and adapt it to the changed conditions

PRODUCTS AND RESEARCH

14 Exploring the chemistry behind silicone-based release additives — Thorsten Schierle
The methods of obtaining and mechanism of action of release additives based on silicones are described. Given the comparison of properties of non-crosslinkable and crosslinkable addditives. It is shown that the presence of the acrylic functional groups increases the degree of crosslinking and minimizes the possibility of migration of components, and longer-lasting surface effects can be achieved. Described the approach to create
formulations of release coatings.
Keywords: silicones, release additives, acrylic functional groups, radiation-curing systems

METHODS OF TESTING
20 A method for controlling the development of corrosion on samples of steel with a paint coating — Ph.D. in physicomathematical sciences V. O. Startsev, A. S. Frolov
In natural climatic conditions of Gelendzhik were tested the steel specimens with epoxy paint coating with cuts on the surface. Presents a method of controlling the spread of corrosion from cut with the help of image analysis corroded surface.
Keywords: climatic testing, corrosion, steel, paint, cut, image analysis

RAW MATERIALS. INTERMEDIATES AND PRODUCTS

24 Acrylic and styrene-acrylic water dispersion in the formulations of paints for painting metal — S. M. Pavlikova, Ph.D. S. V. Anisimova, U. N. Shurigina
The possibilities of the use of acrylic and styrene-acrylic aqueous dispersions as binders in paint compositions for anti-corrosion paint metals. Proven protective properties of coatings based on a polymer products manufacturing Company Homa.
Keywords: acrylic dispersion, styrene-acrylic dispersion, anticorrosion materials

29 Modifed thiokol compositions and their use as waterproofng and protective paint coatings — Dr. Sc. I. P. Storozhuk, Ph.D. N. G. Pavlyukovich
Described a method of modifying thiokol compositions with epoxy resins. Materials in the form of interpenetrating chemical grids with increased strength and adhesion properties were obtained as a result of joint curing thiokol oligomers under the action of manganese dioxide and epoxy oligomers under the influence of amine hardeners.
Keywords: thiokol compositions, epoxy, waterproofng, adhesion

34 Synthesia pigments for powder paints — Lenka Khlostova, Tstirad Yeglik, Leonid Buziner
Described classic and HP pigments for powder coatings. Defined the scope and selection criteria depending on the temperature profile. Given the start formulations of RAL colours for polyester powder paints.
Keywords: pigments, powder coatings, the temperature profle

37 New problems and solutions for manufactures of alkyd coatings. Antioxidants. Anti-skinning additives — Ph.D. V. S Kaverinsky, D. V. Kaverinsky

EVENTS

17 Glintwein from homa — 2017 — O. M. Andrutskaya

40 Raw materials market novelties are in the focus of Coatings Forum — O. M. Andrutskaya

44 YOUR NAVIGATOR
3/2017
3/2017
CONTENT

4, 83 NEWS

ECONOMICS AND STATISTICS
6 The Russian paints and varnishes market in 2016 – Olga Andrutskaya

BRANCH MARKETING
10 Forecast of development of Russian market of water-dispersion paints and varnishes until 2020 with breakdown into segments the segments — PhD Julia Kislova

POINT OF VIEW
18 Chemical distribution in Russia: not bad 2016 and optimistic 2017 — Yuri Ivanov

TINTING TECHNOLOGY. COLORIMETRICS
32 Stability of the CROMSHADE CB 711 LW, a colour paste based on Carbon Black

PRODUCTS AND RESEARCH
34 Anti-corrosion properties of coatings with manganese compounds pigmentation, obtained by ceramic method — Phd, associate
professor M. R. Ziganshina, PhD, prof. S. N. Stepin

56 Low surface energy UV-curable powder coatings — PhD, prof. L. N. Mashlyakovsky, PhD P. B. Pirozhnikov, PhD I. V. Korolev, PhD
N. G. Kuzina, PhD E. V. Khomko

68 Water-dispersed anticorrosion primer based on epoxy emulsion, nanoparticles and crosslinking agent EPILINK 701 — PhD
E. V. Shinkareva

RAW MATERIALS. INTERMEDIATES AND PRODUCTS

22 Painting of composite materials – PhD Andrey Drinberg

42 Water-based coatings — Natalya Kulikova

46 Paint production for pre-painting in Russia — Dr. I. D. Kuleshova

TECHNOLOGIES AND EQUIPMENT

52 Non-waste managed synthesis technology for ZnO to obtain a product with different dispersity — I. A. Estrin, I. V. Koretsky

80 YOUR NAVIGATOR
1-2/2017
1-2/2017
CONTENT

4, 16, 62 NEWS

POINT OF VIEW
12 The Russian market of titanium dioxide: after «Titanic» or towards new horizons? — Yu. E. Ivanov

18 Mergers and acquisitions in the west and their impact on the Russian paint market — G. V. Averyanov

ENVIRONMENT AND RESOURCE
17 Safe future

PRODUCTS AND RESEARCH
25 Synthetic composite fillers and their properties — Dr. L. G. Gerasimov, Ph. D. M. V. Maslovа, Ph. D. E. S. Shchukinа, Yu. G. Kiselev

40 The influence of pentaerythritol’s properties on thermolysis of flame retardant intumescent paints — Ph.D. O. A. Zybina, R. A. Gavakhunova, Dr. Sci. Tech. O. E. Babkin, Dr. Sci. Tech. M. V. Silnikov

44 Long-term corrosion protection of the passenger carriages: problem analysis — A. I. Simonov, Ph. D. T. A. Romanova

48 Coating for cathodic electrodeposition based on polyelectrolyte film former and zinc acetate — A. V. Pavlov, Ph. D. M. Yu. Kvasnikov,
N. O. Baranov, A. D. Zelensky, R. S. Batalov

54 A study of the sorption capacity of the water-soluble ureaformaldehyde oligomers having different aggregate stability, on
the ceramic surface — Ph. D. G. N. Papulova

RAW MATERIALS. INTERMEDIATES AND MATERIALS

20 Silicone modifiers for polyurethane coatings with improved properties — Ph. D. D. Chernyshov

33 New solutions for corrosion protection — Ph. D. V. S. Kaverinsky, D. V. Kaverinsky

51 Coating for glued laminated timber — Dr. A. S. Drinberg, T. E. Vyzhletsova

EVENTS

30 New equipment by «TEKSA Khimmash» — O. M. Andrutskaya

36 International Coatings Forum

58 YOUR NAVIGATOR
12/2016
12/2016
4, 55 NEWS

ECONOMICS AND STATISTICS

10 Russian industry is expected to rise

12 Market of paints in Kazakhstan: it is impossible to lose the prospects for cooperation

17 European market of coil-coatings

POINT OF VIEW

16 UV-resistant coil-coatings: what material is best?

AUTOMATION

29 What interferes in right mixing? Audit of formulation automation

TECHNOLOGY AND EQUIPMENT

32 In the new year COROB RUS company is launching a new service program

PRODUCTS AND RESEARCH

25 UV-curable hybrid sol-gel coating to protect the aluminum
Tested the combination of the UV-cured hybrid sol-gel coatings in order to find an effective replacement for chromium-containing coatings. Hybrid sol-gel coatings demonstrated good passive protection against corrosion on metal substrates due to its good adhesion and ability to form a thick barrier to corrosive substances. This single-step process combines a photoinduced sol-gel process and a cationic (or free-radical) organic photopolymerization.
Keywords: chromium-containing coating, the sol-gel coating, corrosion

34 Low-toxic polyesterurethane coating for corrosion protection of aircraft equipment – Dr. Sci. in Physics and Mathematics, academician of NAS of Azerbaijan A. M. Pashayev, doctor of technical Sciences, Professor T. I. Nizamov, N. F. Javadov, A. A. Aliyev
Ecotoxicological aspects of aircraft topcoats are considered. New protective two-component polyester urethane compound is proposed. New developed technology reduces the polymerization time in the synthesis of polyester and eliminating its toxic smell and a yellowish tinge.
Keywords: aircraft, paint, coating, corrosion, toxicity, polyester urethane compound (PEUC), varnish smell, transparency, odorometry, polymerization

RAW MATERIALS. INTERMEDIATES AND MATERIALS

20 Resins for paints and varnishes for rolled metal — U. V. Galkina
The properties of epoxy and polyester resins for the production the coil-coatings are considered. Described the enamel and primer for painting front and back side of the rolled metal. It is shown that the coatings for front side has an optimal ratio of hardness and elasticity with excellent weather resistance, and primer — perfect corrosion resistance, good adhesion, high flexibility and impact resistance.
Keywords: coil-coating, polyester resins, epoxy resins, polyurethanes

38 New coatings for construction and industry — Dr. A. Drinberg
Considered the new oligomer based on unsaturated polyesters (UPE), modified by paramethylstyrene. Such a polyester film-forming due to residues of unsaturated double bonds combines the versatility of alkyd resins with excellent protective and physico-mechanical properties characteristic of epoxy, vinyl, acrylic and other resins. On the basis of UPE were obtained aqueous dispersion coatings, which compared to a conventional waterbased paints have several advantages: high hardness, rapid drying, and coatings on their basis — high gloss and weather resistance. Described new materials with special properties: anti-icing, super hydrophobic, resistant to radiation.
Keywords: polyesters, alkyds, resins, enamel

EVENTS

24 Belarusian «Lakokraska» introduced new anti-corrosion solutions

42 Experts discussed the prospects of the chemical industry in Russia

ANNIVERSARIES

44 Finest hour of Orghimprom enterprisе — O. M. Andrutskaya

46 Association «Tsentrlak» — from birth to the present day — O. M. Andrutskaya

49 YOUR NAVIGATOR

52 INDEX OF ARTICLES PUBLISHED IN 2016

11/2016
11/2016
4, 47 NEWS

QUESTIONS AND ANSWERS

37 Ask the colorist

NANOTECHNOLOGY

9 Nanodiamonds to improve the properties of polymeric materials

12 Anti-corrosive properties of coatings with nanoparticles

TECHNOLOGIES AND EQUIPMENT

16 Dispensers COROBTM MODULA and the MIXING STATION for industrial tinting and packing paints

PRODUCTS AND RESEARCH
18 An enhancement of the sedimental stability of epoxy zincfilled primers by means of the surface modification of zinc particles — Ph. D. S. N. Stepin, Ph. D. S. I. Tolstosheeva

28 Alkylated by vinyl toluene alkyd oligomers for paint photopolymerizable compositions — Ph. D. O. E. Babkin, V. V. Il’ina, D. V. Pankin, L. A. Babkina, I. V. Sedova

EVENTS

22 Time for innovations

25 To hear customer — O. M. Andrutskaya

40 International exhibition Chemistry–2016

43 The IV International Chemical Forum

POINT OF VIEW

34 Is titanium dioxide carcinogen?!

SUSTAINABILITY AND RESOURCE EFFICIENCY

37 New technology of solvent reduction

44 YOUR NAVIGATOR
10/2016
10/2016
CONTENT

4, 46 NEWS

ECONOMICS AND STATISTICS

10 Consolidation is the future of coating industry
EVENTS

14 And want, and fear — O. M. Andrutskaya

38 Kansai Paint officially presented in Russia

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

19 Hardeners for epoxy systems — Yu. V. Galkina

29 Keeping the look

METHODS OF TESTING

22 Accelerated wear resistant test for traffic marking paints

40 To get rid of the microorganisms

POINT OF VIEW

32 Coatings for pipeline in Russia: opinion of foreigner

QUESTIONS AND ANSWERS

37 Ask the colorist

43 YOUR NAVIGATOR
9/2016
9/2016
CONTENT

4, 50 NEWS

ANNIVERSARIES

10 Chemist and businessman

ECONOMICS AND STATISTICS

16 With a plus — O. M. Andrutskaya

20 The Ukrainian paints and varnishes market in crisis conditions

COMPANY’S PORTRAIT

15 AKZONOBEL localizes the production of protective and marine coatingsin Russia

24 Natural innovation — NANOPrô from Kova

TECHNOLOGIES AND EQUIPMENT

30 Automatic colorants dispensers — COROBTM D600 and D800 is a great combination of high performance, reliability and versatility

EVENTS

32 The first virtual international exhibition «Chemical industry–2016»

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

28 Self-healing coatings — Y. V. Galkina

34 Quality — the key to long life in the market

38 New problems and solutions for manufactures of alkyd coatings. Cobalt driers

44 Polycarbonate diol as raw material for polyurethane compositions — Ph. D. V. S. Kaverinsky, D. V. Kaverinsky

QUESTIONS AND ANSWERS

42 Ask the colorist

47 YOUR NAVIGATOR

КНИГ
на
www.paint-
7-8/2016
7-8/2016
CONTENT

4, 63 NEWS

ECONOMICS AND STATISTICS

12 The Russian market of titanium dioxide for coatings: past, present and future — Ph.D. in economics N. V. Timofeev

TECHNOLOGIES AND EQUIPMENT

16 Automatic colorants dispenser Corob D 300ТМ. Reliable tool for tinting business

23 Preparation of zinc oxide with a given dispersity — I. V. Koretsky, Ph.D. I. A. Estrin

TINTING TECHNOLOGY AND COLORIMETRICS

18 Make exterior paint colourful with inorganic pigments — Ph.D. Filippo Busolo

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

26 The dispersing and wetting additives — N. G. Kulikova

29 Optimization the properties of the base paints with additives Elementis Specialties — T. Etko

34 The best for red and yellow — a new additive technology for waterborne iron oxide pigment concentrates — Frank Kleinsteinberg, Markus Vogel

POINT OF VIEW

32 Foreign producers adapted to new conditions in the Russian coatings market

54 The improved properties of the coating through the use of nano-additives: myth or reality? — M. M. Chernyshova, I. N. Tarasova, Ph.D. A. S. Drinberg

PRODUCTS AND RESEARCH

41 The adhesive composition based on an aqueous emulsion for epoxy system «TERMOSHUBA» — Ph.D. E. V. Shinkareva

45 Synthesis and modification of epoxy-acrylate resins — N. S. Petrov, Ph.D. E. V. Sivtsov

51 Influence of surfactants, wetting the alumina surfaces — prof., Ph.D., S. V. Dobrydnev, О. А. Abu Amria, M. Yu. Molodtsova

EVENTS

58 Modern ways of corrosion protection presented in St. Petersburg

60 YOUR NAVIGATOR
6/2016
6/2016
NEWS

ECONOMICS AND STATISTICS

8 What’s new in the resins market?

SUSTAINABILITY AND RESOURCE EFFICIENCY

10 Long life of old idea: new trends — Ph. D. V. S. Kaverinski, D. V. Kaverinski

EVENTS

14 Business and High School — course on convergence

18 DAW-Russland opened fi rst Caparol Academy in Russia

24 Russian furniture manufacturers are going to replace the imported paints

49 MOSBUILD updates — O. M. Andrutskaya

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

15 Modern solutions in two-component polyurethane systems for metal protection — U. V. Galkina

27 High-temperature corrosion polyurethane-polyurea coatings for oil and gas pipelines and fi ttings — E. V. Guseva, A. A. Keresten, Prof. V. V. Zuev

PRODUCTS AND RESEARCH

20 Impact strength of epoxy coatings cured with aminophenolic hardener — Ph. D., prof. V. T. Erofeev, Ph. D. I. V. Smirnov, Ph. D. V. V. Erastov, O.V. Startsev, A.Ju. Makhon’kov

32 An integrated system of coatings for protection of metal, polymer composite materials, as well as their contact connections from exposure to corrosive factors — Academician of RAS, doctor of technical Sciences E. N. Kablov, Ph. D. L. V. Semenova, Ph. D. A. A. Es'kov, T. A. Lebedeva

42 Adhesive based on an aqueous emulsion of an epoxy carbon fiber to strengthen the load-bearing reinforced concrete structures — Ph. D. E. V. Shinkareva

POWDER COATINGS

36 The influence of the nature of the components of the powder epoxy — fluoropolymer compositions and the conditions of film formation on the
hydro/oleophobicity and surface properties of coatings — N. S. Kozmina, Ph. D. N. A. Egorova, Ph. D. E. V. Homko, Ph. D., prof. L. N. Maschlyakovsky

52 YOUR NAVIGATOR
5/2016
5/2016
CONTENT
4 NEWS

ECONOMICS AND STATISTICS

10 Market of marine and protective paints and varnishes — Ph. D. V. S. Kaverinsky, D. V. Kaverinsky

19 Only one fuel and energy complex... Russian companies go into the production of anti-corrosion coatings for large diameter pipes — Olga Khoreva

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

14 Protective coatings based on epoxy resins — Yu. V. Galkina

22 PROFGUARD — the professional protection of metal structures

PRODUCTS AND RESEARCH

16 Thermal properties polyhydroxyethers — D. A. Beeva, A. A. Beev, A. H. Salamov, L. G. Grineva

26 Quantum-chemical and statistical study of the mechanism of action of organic compounds as corrosion inhibitors — A. A. Sikachina

32 Water epoxy emulsions — Ph. D. E. V. Shinkareva, Ph. D. V. D. Koshevar, Ph. D. N. L. Budeiko

46 Influence of ratio of polar and nonpolar groups in the monomers on the properties of theUV-curable protective coating — Doctor of Tech. Sci. O. E. Babkin, A. V. Zhdanova

TINTING TECHNOLOGY AND COLORIMETRICS

30 What Pass/Fail strategy is the most appropriate for you? — Stanislav Šulla

EXPERT VIEW

41 Coatings durability estimation problem in the oil and gas industry — E. A. Eselev, E. I. Polyakova

TECHNOLOGIES AND EQUIPMENT

49 The concept of innovation «Paint-technology» and its practical implementation — Doctor of Tech. Sci. V. V. Menshikov, V. A. Rybkin

EVENTS

56 Exhibition «Interlakokraska» in the year of anniversary — O. M. Andrutskaya

62 YOUR NAVIGATOR
4/2016
4/2016
CONTENTS

4, 55 NEWS

SUSTAINABILITY AND RESOURCE EFFICIENCY

8 Prices for oil and biomaterials for paints and varnishes market

STANDARDIZATION AND METROLOGY

10 Russian sign of quality comes in the paint industry — V. N. Abramov, S. P. Ermilov, E. A. Saratseva

INTERVIEW

13 Industry needs a dialogue with the consumer and the government

METHODS OF TESTING
15 Preparation of aqueous alkyd emulsions in the presence of a nonionic surfactant and solid microparticles of organic nature — Ph.D. E. V. Shinkareva
Results of research of stability of water emulsions of the alkyd resin modified by vegetable oil depending on concentration of emulsifiers and an oil phase are presented. Hardness the alkyd coatings is studied.
Keywords: alkyd resin, water emulsion, colloids, surfactants

RAW MATERIALS, INTERMEDIATES AND PRODUCTS
23 High quality dispersions as the basis for modern waterbazed materials —N. G. Kulikova
Considered acrylic, styrene acrylic, urethane, alkyd and urethane aqueous dispersions, their properties and uses. A universal primer with a sealing effect on the basis of acrylic dispersion. The tests of the depth of penetration on wood and mineral substrate are carried out.
Keywords: aqueous dispersions, acrylic dispersions, acrylic primer

26 Constructional fire protection of steel structures with reduced metal thickness of less than 5.8 mm — Myth or Reality? — L. I. Nateykina,
E. A. Shikhaliyev
A comparison of thin-layer materials and structural fire protection, fire-retardant material selection criteria are described. Samples of flame retardant materials presents on the Russian market, defined physical and technical characteristics and flame retardants were tested. Based on these results, it was revealed a discrepancy of some materials to the specs.
Keywords: paints, fire-retardant coating, structural fire protection

40 Mineralogical base of technological properties of yellow-brown iron oxide «BELFEROKS» pigments from natural ores — Ph.D. A. V. Kochergin, Ph.D., Associate Professor N. V. Granovskaya
We obtained yellow, brown and red opaque pigments and transparent pigments, similar to the classic umbra, from natural pigment ores of Beloretsk region of Bashkortostan. «Belferoks» pigments are characterized by low oil absorption, high chemical resistance, relatively high intensity and spreading capacity. The studies are cover pigments with yellow-brown color spectrum and umbra. Mineralogical characteristics and technological properties researches of pigment products conduct by the complex of methods (chemical, X-ray and thermal assay, transmission and scanning electron microscopy, IR and Mössbauer spectroscopy, colorimetry, technological testing). Pigmented substance in all types of pigments is represented by alpha iron hydroxide (goethite). Most of the goethite of «Belferoks» pigments unclearly is crystallized with a crystallite dimensions from tens to hundreds of nanometers. The principal role in yellowbrown «Belferoks» pigments color variations belongs to a manganese value and its localization in iron hydroxides. «Belferoks» umbra are differ a high degree of crystallinity when it high dispersity. The black color in combination with umbra’s transparency explained by the light absorption.
Keywords: iron oxide pigments, the natural pigment ores, iron hydroxides, mineralogy of pigments

TINTING TECHNOLOGY AND COLORIMETRICS

34 Instrumental determination of color strength of colorants — P. P. Novoseltsev
The analysis of the methods for determining the color strength is made, the basic standard procedure of instrument definition color strength of colorants are described, their advantages and disadvantages are discussed. The recommendations on the choice of methodology in accordance with the tasks: in-process control or comparative tests of different colorants.
Keywords: colorants, coloring strength, chromophores, the color difference

38 Discover the efficiency of the professional color formulation —Stanislav Šulla

EVENTS
31 Mulled wine from homa®. VI Annual Scientific Conference

45 Every technologist wants to know... — O.M. Andrutskaya

52 YOUR NAVIGATOR
3/2016
3/2016
CONTENT

4, 55 NEWS

ECONOMICS AND STATISTICS

8 Market of construction paints

EXPERT OPINION

10 «Do it yourself» — for smart and poor, «do it for me» — for wealthy shirkers?

RAW MATERIALS. INTERMEDIATES AND MATERIALS

13 Raw materials that improve the properties of decorative paints and varnishes — N. G. Kulikova

20 Gloss German style

22 Minimum thickness of fi re-retardant coating of intumescent type — L. I. Nateykina

28 The possibility of using synthetic barium sulfate to improve the optical properties of paints and varnishes for construction application — V. V. Volodina, V. V. Repin

30 Less yellowing due to the sealing knots — Gun Lundsten

33 Defoamers and additives ROWISTM for increasing open time — Božena Zydek, Anna Ogneva

TINTING TECHNOLOGY. COLORIMETRY

16 Luconyl® — high-quality pigment pastes earmarked for pigmenting waterborne paints and varnishes — Stephen Gilligan

TECHNOLOGY AND EQUIPMENT

18 At the roots of creation of tinting equipment.

ENVIRONMENT AND RESOURCES

25 The remains of decorative paints as the source of profit

PRODUCTS AND RESEARCH

38 Water-repellent material based on aqueous epoxy emulsion and adductive curing agent — E. V. Shinkareva, V. D. Koshevar

42 Aproaches to formulating LED curable materials — prof., Ph.D. O.E. Babkin, L. A. Babkina, A. V. Arabei, I. Birks

STANDARDIZATION AND METROLOGY

48 On new standards for modern paints and coatings systems based on them — Prof. prof. P. V. Nikolaev, Ph. D. E. Konstantinov

52 YOUR NAVIGATOR
1-2/2016
1-2/2016
CONTENT

4, 87 NEWS

ECONOMICS AND STATISTICS

10 Russian paint and coatings industry in 2015 — O. M. Andrutskaya

50 Four major end-markets for self-healing materials — Jim Montgomery

STANDARDIZATION AND METROLOGY

12 What is important to know for manufacturers and importers of chemical products before implementation technical regulations of the Eurasian economic Union — O. A. Afanasievа

RAW MATERIALS, INTERMEDIATES AND PRODUCTS

24 The import substitution in the coatings industry is possible for the Russian manufacturers

27 Colour Development and Low Viscosity Polymeric Dispersing Agents in Solvent-Based Industrial Coatings — Christopher Williams

52 NEW! Constructive fi re protection Neofl ame® — L. I. Nateikina, Ph.D. V. P. Pimenova

58 Additional polymer coating to protect galvanized crimped culverts — I. A. Susorov, G. S. Royak, V. S. Dobkin

80 The use of polymer coatings as absorber of laser radiation — Associate Professor, Ph.D. V. I. Shustin, Prof., Dr. N. P. Konovalov

COMPANY’S PORTRAIT

16 The leader of the Egyptian chemical industry is coming to Russia

INTERVIEW

22 Nuplex is the right partner for import substitution

TECHNOLOGIES AND EQUIPMENT

36 Automatic dispenser of colorants COROB D 200TM is an optimal entry-level solution for tinting at the point of sale

41 Laboratory equipment, control devices — Yu. V. Galkina

48 Pumps of volume fl ow for paint industries. What is better: pneumatic or electric? — A. V. Kharitonov

EVENTS

30 All shades of white — O. M. Andrutskaya

44 International Coatings Forum

TINTING TECHNOLOGY AND COLORIMETRICS

34 New technology in color measurement

38 Perfect Calibration Data — A Spring Board to a Successful Paint Formulation — Stanislav Šulla

NANOTECHNOLOGY

63 Nanodispersed polytetrafl uoroethylene ForumTM and its impact on the physical characteristics of paint coatings — Ph.D. A. K. Tsvetnikov,
L. A. Matveenko, Ph.D. A. B. Puz', Ph.D. V. S. Egorkin, Ph.D. B. A. Golub, Ph.D. S.I. Maslennikov, A.D. Pavlov, Prof. S.V. Gnedenkov

SUSTAINABILITY AND RESOURCE EFFICIENCY

72 Wastes from the production of powder paints and coatings and their disposal — Ph.D. D. A. Yakovlev, Ph.D. A. V. Il'inykh

EXPERT VIEW

76 Factors aff ecting the development of the Russian production of adhesives and sealants — Ph.D. I. K. Khairullin

PRODUCTS AND RESEARCH
18 Emulsifier free film-forming acrylate latexes— A. S. Serdtselyubova, Prof. I. A. Tolmachev, V. K. Vasiliev

54 Features thermolytic degradation of polyvinyl alcohol and polyvinyl chloride — S. A. Shumilov, A. V. Varlamov, O. A. Zybina, O. E. Babkin, S. S. Mnatsakanov

68 Structure and properties of zinc-polymer paint coatings obtained by simultaneous electrodeposition at the cathode of the amine polyelectrolyte and zinc — А.V. Pavlov, Ph.D. M. Yu. Kvasnikov, Ph.D. I. F. Utkina, Yu. V. Milyutina, A. S. Merkulova, A. V. Pozharitskaya, D.Sc. Yu. M. Korolev

84 YOUR NAVIGATOR
12/2015
12/2015
CONTENT

4, 56 NEWS

ECONOMICS AND STATISTICS

8 The online sales of coatings in Russia

STANDARDIZATION AND METROLOGY

9 Standardization of terminology of coatings — F. I. Ildarhanova, K. G. Bogoslovsky

RAW MATERIALS. INTERMEDIATES AND PRODUCTS

13 Pigments and functional fillers for powder coatings from «AFAYA» — L. J. Businer

20 Eco-friendly raw materials for manufacturing eco-friendly paints — N. G. Kulikova

38 Fire resistant materials NEОFLAME® — L. I. Nateikina, V. P. Pimenova

POWDER COATINGS

16 UV-curable powder coatings for heat-sensitive surfaces

TINTING TECHNOLOGY AND COLORIMETRY

24 Constructive aspects of spectrophotometers: what measurement geometry should you choose? — Stanislav Šulla

EVENTS

26 Wide scope, individual approach — O. M. Andrutskaya

44 The exhibition «Chemistry» in the year of the triple jubilee

47 Chemists discuss strategy of industry

PRODUCTS AND RESEARCH

30 Preparation and properties of thermochromic coatings based on acrylic polymer emulsions and coordination compounds of iron(II) with tris(pyrazol-1-yl)methane — L. F. Abrosimova, O. G. Shakirova

34 Оptimization of zinc-rich powder protective coatings properties — S. I. Tolstosheeva, S. N. Stepin, A. P. Svetlakov

50 YOUR NAVIGATOR

53 INDEX OF ARTICLES 2015
11/2015
11/2015
4, 53 NEWS

ECONOMICS AND STATISTICS

8 Russian Coatings Industry. Results of 9 month 2015 — O. M. Andrutskaya

RAW MATERIALS. INTERMEDIATES AND PRODUCTS

11 Additives for aqueous and solvent based coatings for protection, improving properties, curing and rheology. — Yu. V. Galkina

15 Wax additives by MÜNZING CHEMIE GmbH

18 FAE as alternative to APE?

20 Xynpol AO557L or waterproof membranes and wood coatings

EVENTS AND FACTS

25 The global market of titanium dioxide: history and prospects — M. Bisengaliev, N. Timofeev

EVENTS

30 Openness to partnership — O. M. Andrutskaya

NANOTECHNOLOGY

34 Nanocoatings and technology in paint industry — V. S. Kaverinsky, D. V. Kaverinsky

38 Magnificent Dwarfs. Nanotechnology Regulation in the European Union — Dietmar Eichstädt

EXPERT VIEW

41 Expert opinion about the choice of dispersing additives

TINTING TECHNOLOGY AND COLORIMETRY

42 Why do we need to measure colors? And how? — Stanislav Šulla

PRODUCTS AND RESEARCH

44 Highly hydrophobic coatings from powder epoxy-fluoropolymer compositions— L. N. Mashlyakovsky, N. S. Gvozdikova, N. A. Egorova, E. V. Khomko

50 YOUR NAVIGATOR

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